link Formula molecular Weight Appearance melting Point boiling Point Density Solubility in H2O precise Mass Monoisotopic Mass
Yellow pieces
>500 °C
2.055 g/cm3
call with water releases flammable gas

Signal Word peril Statements risk Codes precautionary Statements risk Codes security Statements move Information GHS Pictograms
F, T+, Xn, N
UN2011 4.3 (6.1)/PG I





Product Name: Magnesium Phosphide

Product Number: all applicable American elements product codes, e.g. MG-P-02, MG-P-03, MG-P-04, MG-P-TG

CAS #: 12057-74-8

Relevant figured out uses the the substance: clinical research and development

Emergency call number:Domestic, phibìc America: +1 800-424-9300International: +1 703-527-3887


2.1. Group of the problem or mixtureIndications that danger: F - very flammable, T+ - an extremely toxic, Xn - Harmful, N - Dangerous because that theenvironmentR phrases:Contact with water liberates toxic, very flammable gas.Harmful in call with skin.Very toxic by inhalation, in call with skin and also if swallowed.Contact v acids liberates really toxic gas.Very toxic to aquatic organisms.developed with humidity, gaseous phosphineGHS classificationHazard categories:Substance or mixture which in contact with water emits flammable gas: Water-react. 1Acute toxicity: Acute Tox. 1Acute toxicity: Acute Tox. 2Serious eye damage/eye irritation: Eye Irrit. 2Hazardous to the aquatic environment: Aquatic Acute 12.2. Brand elementsSignal word: DangerPictograms: GHS02-GHS06-GHS09


Hazard Statements:H260 In contact with water release flammable gases which might ignite spontaneously.H300 deadly if swallowed.H330 deadly if inhaled.H311 toxic in contact with skin.H400 an extremely toxic come aquatic life.Precautionary statementsP223 carry out not enable contact v water.P232 safeguard from moisture.P234 Keep only in initial container.P273 stop release come the environment.P280 Wear perfect protective clothing, gloves and eye/face protection.P301+P310 IF SWALLOWED: instantly call a toxicity CENTER/doctor.P321 particular treatment (see very first Aid on this label).P335 Brush off loose particles native skin.P370+P378 In situation of fire: use Carbon dioxide (CO2).; Sand; Extinguishing powder. Come extinguish.P402+P404 keep in a dried place. Keep in a closeup of the door container.P405 keep locked up.P501 Dispose of this material and its container come hazardous or distinct waste repertoire point.Special labelling of details mixturesEUH029 call with water liberates toxicity gas.EUH032 contact with mountain liberates very toxic gas.Substances or mixture which, in contact with water emit flammable gases: Phosphinedeveloped with humidity, gaseous phosphine


Magnesium PhosphideCas No.: 12057-74-8Formula: Mg3P2


Description of first aid measuresGeneral informationImmediately remove any type of clothing soiled through the product.In case of irregular breathing or respiratory tract arrest carry out artificial respiration.After inhalationSupply fresh air. If required, carry out artificial respiration. Store patient warm.Seek prompt medical advice.After skin contactImmediately wash through water and soap and also rinse thoroughly.Seek instant medical advice.After eye contactRinse opened up eye for number of minutes under to run water. Then consult a doctor.After swallowingDo no induce vomiting; immediately call for medical help.Information for doctorMost essential symptoms and effects, both acute and delayedNo further relevant information available.Indication of any type of immediate clinical attention and also special therapy neededNo further relevant info available.

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Extinguishing mediaSuitable extinguishing agentsCO2, sand, extinguishing powder. Perform not use water.For safety factors unsuitable extinguishing agentsWaterSpecial hazards emerging from the problem or mixtureIf this product is involved in a fire, the following can it is in released:Metal oxide fumePhosphorus oxidesAdvice for firefightersProtective equipment:Wear self-contained respirator.Wear totally protective impervious suit.


Personal precautions, protective equipment and emergency proceduresMount respiratory tract protective device.Wear security equipment. Keep unprotected persons away.Ensure adequate ventilationKeep away from ignition sourcesEnvironmental precautions:Do not allow material to be exit to the atmosphere without proper governmental permits.Do not allow product to with sewage mechanism or any water course.Do not allow to penetrate the ground/soil.Methods and also material for containment and also cleaning up:Keep far from ignition sources.Dispose of contaminated product as waste according to section 13.Ensure sufficient ventilation.Do not flush through water or aqueous cleansing agentsPrevention of an additional hazards:Keep far from ignition sources.Reference to various other sectionsSee ar 7 for information on safe handlingSee ar 8 for info on personal protection equipment.See ar 13 for disposal information.


HandlingPrecautions for for sure handlingHandle under dry protective gas.Keep container strict sealed.Store in cool, dry location in tightly close up door containers.Ensure good ventilation at the workplace.Information around protection versus explosions and also fires:The product is no flammableConditions for for sure storage, including any kind of incompatibilitiesStorageRequirements to be met by storerooms and also receptacles:No distinct requirements.Information about storage in one usual storage facility:Store far from oxidizing agents.Do no store along with acids.Store away from water/moisture.Further information about storage conditions:Store under dried inert gas.This product is moisture sensitive.Keep container tightly sealed.Store in cool, dry problems in fine sealed containers.Protect indigenous humidity and also water.Specific finish use(s)No further relevant details available


Additional information about design of technical systems:Properly operation chemical fume hood designed for hazardous chemicals and also having one average confront velocity the at the very least 100 feet per minute.Control parametersComponents through limit values that require monitoring at the workplace:Not required.Additional information:No dataExposure controlsPersonal safety equipmentGeneral protective and hygienic measuresThe usual precautionary steps for dealing with chemicals have to be followed.Keep away from foodstuffs, beverages and feed.Remove every soiled and contaminated apparel immediately.Wash hands before breaks and at the end of work.Maintain an ergonomically appropriate working environment.Breathing equipment:Use an ideal respirator as soon as high concentrations space present.Protection the hands:Impervious glovesCheck protective gloves prior to each use for their proper condition.The selection of suitable gloves not only depends top top the material, but likewise on quality. High quality will differ from manufacturer to manufacturer.Penetration time that glove product (in minutes)Not determinedEye protection:Safety glassesFull face protectionBody protection:Protective work-related clothing.


Information on straightforward physical and also chemical propertiesGeneral InformationAppearance:Form: PiecesOdor: Garlic-likeOdor threshold: no determined.pH-value: no applicable.Change in conditionMelting point/Melting range: > 500(Phosphine) °CBoiling point/Boiling range: no determinedSublimation temperature / start: not determinedFlammability (solid, gaseous)Contact with water liberates extremely flammable gases.Ignition temperature: no determinedDecomposition temperature: no determinedAuto igniting: not determined.Danger of explosion: no determined.Explosion limits:Lower: not determinedUpper: no determinedVapor pressure: no applicable.Relative densityNot determined.Vapor densityNot applicable.Evaporation rateNot applicable.Solubility in / Miscibility with Water: contact with water releases flammable gasesPartition coefficient (n-octanol/water): not determined.Viscosity:dynamic: not applicable.kinematic: no applicable.Other informationNo more relevant information available


ReactivityIn contact with water releases flammable gases which may ignite spontaneously.Contact with acids liberates very toxic gas.Chemical stabilityStable under recommended storage conditions.Thermal decomposition / conditions to it is in avoided:Decomposition will not happen if used and also stored follow to specifications.Possibility of hazardous reactionsContact with water releases flammable gasesContact through water releases toxicity gasesContact through acids releases toxicity gasesContact through acids liberates very toxic gas.Conditions come avoidNo additional relevant details available.Incompatible materials:AcidsWater/moistureHazardous decomposition products:Metal oxide fumePhosphorus oxides (e.g. P2O5)


Information ~ above toxicological effectsAcute toxicity:Fatal if swallowed.The registry of Toxic results of chemical Substances (RTECS) includes acute toxicity data for contents in this product.LD/LC50 worths that are appropriate for classification:Oral LD50 12 mg/kg (rat)Skin irritation or corrosion:May cause irritationEye wake up or corrosion:May cause irritationSensitization:No sensitizing results known.Germ cabinet mutagenicity:No results known.Carcinogenicity:No group data top top carcinogenic properties of this material is easily accessible from the EPA, IARC, NTP, OSHA or ACGIH.Reproductive toxicity:No impacts known.Specific target organ device toxicity - repetitive exposure:No effects known.Specific target organ device toxicity - single exposure:No results known.Aspiration hazard:No results known.Subacute to chronic toxicity:The it is registered of Toxic results of chemistry Substances (RTECS) consists of multiple dose toxicitydata for this substance.Additional toxicological information:To the best of our expertise the acute and chronic toxicity of this substance is not totally known.


ToxicityAquatic toxicity:No more relevant info available.Persistence and degradabilityNo more relevant information available.Bioaccumulative potentialNo additional relevant information available.Mobility in soilNo additional relevant details available.Ecotoxical effects:Remark:Very toxicity for aquatic organismsAdditional environmental information:General notes:Do not enable material to be released to the environment without proper governmental permits.Do not permit product to reach ground water, water course or sewage system, even in small quantities.Danger to drink water if also extremely tiny quantities leak right into the ground.Also poisonous because that fish and plankton in water bodies.May cause long lasting harmful results to aquatic life.Avoid transfer right into the environment.Very toxicity for aquatic organismsResults the PBT and also vPvB assessmentPBT:Not applicable.vPvB:Not applicable.Other disadvantage effectsNo more relevant details available.

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Waste treatment methodsRecommendationConsult state, regional or national regulations come ensure appropriate disposal.Uncleaned packagings:Recommendation:Disposal must be made follow to main regulations


UN-NumberDOT, IMDG, IATAUN2011UN suitable shipping nameDOTMagnesium phosphideIMDG, IATAMAGNESIUM PHOSPHIDETransport peril class(es)DOTClass4.3 building materials which, in contact with water, emit flammable gases.Label4.3+6.1Class4.3 (WT2) building materials which, in contact with water, emit flammable gasesLabel4.3+6.1IMDG, IATAClass4.3 building materials which, in contact with water, emit flammable gases.Label4.3+6.1Packing groupDOT, IMDG, IATAIEnvironmental hazards: Environmentally hazardous substance, solidSpecial precautions for userWarning: building materials which, in contact with water, emit flammable gasesEMS Number: F-G,S-NSegregation groupsHeavy metals and their salt (including your organometallic compounds)Transport in bulk according come Annex II of MARPOL73/78 and also the IBC CodeNot applicable.Transport/Additional information:DOTMarine Pollutant (DOT):NoUN "Model Regulation":UN2011, Magnesium phosphide, 4.3 (6.1), I


Safety, health and environmental regulations/legislation details for the problem or mixtureNational regulationsAll components of this product are listed in the U.S. Ecological Protection company Toxic Substances control Act chemical substance Inventory.All components of this product are provided on the Canadian Non-Domestic Substances list (NDSL).SARA section 313 (specific toxicity chemical listings)12057-74-8 Magnesium phosphideCalifornia Proposition 65Prop 65 - Chemicals recognized to reason cancerSubstance is no listed.Prop 65 - Developmental toxicitySubstance is no listed.Prop 65 - Developmental toxicity, femaleSubstance is no listed.Prop 65 - Developmental toxicity, maleSubstance is no listed.Information around limitation that use:For use only by technically standard individuals.This product is topic to the reporting demands of section 313 of the Emergency Planning and also Community appropriate to know Act that 1986 and also 40CFR372.Other regulations, limitations and prohibitive regulationsSubstance of really High problem (SVHC) according to the with Regulations (EC) No. 1907/2006.Substance is no listed.The problems of constraints according to article 67 and Annex XVII the the Regulation (EC) No 1907/2006 (REACH) because that the manufacturing, placing on the market and also use must be observed.Substance is no listed.Annex XIV of the reach Regulations (requiring Authorisation because that use)Substance is no listed.REACH - Pre-registered substancesSubstance is listed.Chemical safety assessment:A Chemical security Assessment has actually not been lugged out.